Multideprotonable, ambiphilic and hybrid ligands with electron pool suitable for complexation of various low valent metals
Provider: Grantová agentura ČR
Programme: Standardní projekty
Implementation period: 01.01.17 - 31.12.19
Workplace:
Fakulta chemicko-technologická - Katedra obecné a anorganické chemie
Investigator: Růžička AlešTeam member: Chlupatý Tomáš
Description:
This project is focused to the synthesis of multideprotonable, hybrid and ambiphilic ligands suitable for complexation of metal centres in generally low oxidation states. Suggested ligands are: amidinato/guanidinato ligands combined with N-heterocyclic carbenes, hybrid neutral ligands (betaines), non-innocent imido-amides, oligodeprotonable amidinates/guanidinates, bis-trisamido/bis-trisimido-phosphonates/phosphinates and various amidinate, guanidinate and carbene ligands decorated by R2B group. The use of such ligands in synthesis of coordination compounds of main group, environmentally acceptable and catalytically applicable metals will be the major target of the project along with its use in catalytically driven organic chemistry transformations, and in a part in material science.
This project is focused to the synthesis of multideprotonable, hybrid and ambiphilic ligands suitable for complexation of metal centres in generally low oxidation states. Suggested ligands are: amidinato/guanidinato ligands combined with N-heterocyclic carbenes, hybrid neutral ligands (betaines), non-innocent imido-amides, oligodeprotonable amidinates/guanidinates, bis-trisamido/bis-trisimido-phosphonates/phosphinates and various amidinate, guanidinate and carbene ligands decorated by R2B group. The use of such ligands in synthesis of coordination compounds of main group, environmentally acceptable and catalytically applicable metals will be the major target of the project along with its use in catalytically driven organic chemistry transformations, and in a part in material science.
