Nitrogen Ligands for Main Group Elements - going bulkier, more conjugated and guilty
Provider: Grantová agentura ČR
Programme: Standardní projekty
Implementation period: 01.01.21 - 31.12.23
Workplace:
Fakulta chemicko-technologická - Katedra obecné a anorganické chemie
Investigator: Růžička Aleš
Description:
This project deals with coordination and organometallic chemistry, in particular to compounds of Group 13-15 elements containing novel types of nitrogen ligands, synthesis, structure and reactivity of yet unknown types of species. Bulkiest aniline ligands will stabilize unprecedented bonding patterns of heavier elements as for example terminal or multiple bonding. Next, broad toolkit of the amidinates, guanidinates, in combination with its non-innocent behavior, and/or carbenes will provide the access to low valent and multimetallic species important for activation of small molecules and multiple bonds as well as the formation of molecules suitable for the creation of new materials and electronic devices. Last, the ligands based on amino/imino pyridines or ligands with a doubly chelating manner, and its complexes as masked heterodienes could be used for preparation of several unknown heterocycles.
This project deals with coordination and organometallic chemistry, in particular to compounds of Group 13-15 elements containing novel types of nitrogen ligands, synthesis, structure and reactivity of yet unknown types of species. Bulkiest aniline ligands will stabilize unprecedented bonding patterns of heavier elements as for example terminal or multiple bonding. Next, broad toolkit of the amidinates, guanidinates, in combination with its non-innocent behavior, and/or carbenes will provide the access to low valent and multimetallic species important for activation of small molecules and multiple bonds as well as the formation of molecules suitable for the creation of new materials and electronic devices. Last, the ligands based on amino/imino pyridines or ligands with a doubly chelating manner, and its complexes as masked heterodienes could be used for preparation of several unknown heterocycles.
