Publication detail

The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents.

Year: 2008

Type of publication: článek v odborném periodiku

Name of source: Journal of Fluorine Chemistry

Publisher name: Elsevier Science SA

Place: Lausanne

Page from-to: 167-172

Titles:

Language	Name	Abstract	Keywords
cze	The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents.	The organoantimony(III) difluorides containing Y,C,Y chelating, so called pincer, ligands ([2,6-(YCH2)2C6H3]SbF2; Y = MeO, t-BuO and Me2N ) were prepared by the reaction of corresponding dichlorides ([2,6-(YCH2)2C6H3]SbCl2; Y = MeO, t-BuO and Me2N ) with two equivalents of organotin(IV) fluorinating agents Me3SnF or 2-(Me2NCH2)C6H4Sn(n-Bu2)F, respectively. The structure of organonantimony fluorides was determined both in solution by 1H, 13C and 19F NMR spectroscopy and in the solid state using X-ray diffraction.	Antimony, Fluorine, Tin, Chelating ligand, X-ray structure
eng	The synthesis of organoantimony(III) difluorides containing Y,C,Y pincer type ligands using organotin(IV) fluorinating agents.	The organoantimony(III) difluorides containing Y,C,Y chelating, so called pincer, ligands ([2,6-(YCH2)2C6H3]SbF2; Y = MeO, t-BuO and Me2N ) were prepared by the reaction of corresponding dichlorides ([2,6-(YCH2)2C6H3]SbCl2; Y = MeO, t-BuO and Me2N ) with two equivalents of organotin(IV) fluorinating agents Me3SnF or 2-(Me2NCH2)C6H4Sn(n-Bu2)F, respectively. The structure of organonantimony fluorides was determined both in solution by 1H, 13C and 19F NMR spectroscopy and in the solid state using X-ray diffraction.	Antimony, Fluorine, Tin, Chelating ligand, X-ray structure

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