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An Unified Theory for the Kinetic Analysis of Solid State Reactions under Any Thermal Pathway
Authors: Criado José Manuel | Pérez-Maqueda Luis A. | Gotor Francisco José | Málek Jiří | Koga Nobuyoshi
Year: 2003
Type of publication: článek v odborném periodiku
Name of source: Journal of Thermal Analysis and Calorimetry
Publisher name: Springer
Page from-to: 901-906
Titles:
Language Name Abstract Keywords
cze An Unified Theory for the Kinetic Analysis of Solid State Reactions under Any Thermal Pathway The Ozawa concept of generalized time has been used for developing master plots for the different kinetic models describing solid state reactions. These plots can be indistinctly used for analysing isothermal or non-isothermal experimental data. It is demonstrated that it is not possible to discriminate the kinetic model from a single non-isothermal curve without a previous knowledge of the activation energy. xxxxx
eng An Unified Theory for the Kinetic Analysis of Solid State Reactions under Any Thermal Pathway The Ozawa concept of generalized time has been used for developing master plots for the different kinetic models describing solid state reactions. These plots can be indistinctly used for analysing isothermal or non-isothermal experimental data. It is demonstrated that it is not possible to discriminate the kinetic model from a single non-isothermal curve without a previous knowledge of the activation energy. solid state reactions, theory for the kinetic analysis, thermal pathway