Publication detail

Calculation of Site-specific CO Stretching Frequensies for Copper Carbonyl with the Near Spectroscopic Accuracy: CO Interaction with Cu+/MFI

Authors: Bludský Ota | Šilhan Martin | Nachtigallová Dana | Bulánek Roman | Nachtigall Petr

Year: 2003

Type of publication: ostatní - přednáška nebo poster

Name of source: XXXV. Symposium on Catalysis

Publisher name:

Place:

Page from-to:

Titles:

Language	Name	Abstract	Keywords
cze			xxx
eng	Calculation of Site-specific CO Stretching Frequensies for Copper Carbonyl with the Near Spectroscopic Accuracy: CO Interaction with Cu+/MFI	A scaling method base don the linear correlation between the CO bondlenght and the stretching frequency has been applied to the CO molecule adsorbed on the Cu exchanged MFI zeolite The effect of the Madelung potential on the CO stretching frequencies was found to be negligible. All Cu+ ions on the channel intersection and on the wall of the main channel are characterized by the CO stretching frequencies in the narrow range of 2159-2164 cm-1 in excelent agreement with the experimnetal data.	Cu exchanged MFI zeolite, Co molecules

Search