Publication detail

Structure and Base Catalysed Cyclization of Methyl (2,6-Disubstituted-4-nitrophenylsulphanyl)ethanoates

Authors: Bertolasi Valerio | Dudová Kateřina | Šimůnek Petr | Černý Jiří | Macháček Vladimír

Year: 2003

Type of publication: článek v odborném periodiku

Name of source: Journal of Molecular Structure

Publisher name: Elsevier Science BV

Place: Amsterdam

Page from-to: 33-42

Titles:

Language	Name	Abstract	Keywords
cze	Struktura a bázicky katalyzované cyklizace methyl-(2,6-disubstituovaných-4-nitrofenylsulfanyl)ethanoátů		Methyl (2-X-4,6-dinitrophenyl)sulphanylethanoates, cyclization reactions, X-ray, NMR
eng	Structure and Base Catalysed Cyclization of Methyl (2,6-Disubstituted-4-nitrophenylsulphanyl)ethanoates	The conformation of side chain ?SCH2COOCH3 in title compounds in crystal agrees with the reactivity of these compounds in base-catalysed ring closure in solution. In the 2,4-dinitro derivative, the side chain is oriented towards the unsubstituted ortho-position of benzene ring, in the case of the 2-methoxycarbonyl derivative towards this substituent.	Methyl-(2-X-4,6-dinitrofenyl)sulfanylethanoáty, cyklizační reakce, X-ray, NMR

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