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Structural Study of Tris(N,N-diethyldithiocarbamato-S,S')-3-methoxypropyltin(IV). Searching for Hypercoordinated Monoorganotin(IV) Species
Authors: Zoufalá Petra | Císařová Ivana | Růžička Aleš
Year: 2003
Type of publication: článek v odborném periodiku
Name of source: Main Group Metal Chemistry
Publisher name: Walter de Gruyter GmbH & Co. KG
Place: Berlin
Page from-to: 53-58
Titles:
Language Name Abstract Keywords
cze Structural Study of Tris(N,N-diethyldithiocarbamato-S,S')-3-methoxypropyltin(IV). Searching for Hypercoordinated Monoorganotin(IV) Species Tris(N,N-diethyldithiocarbamato-S,S')-3-methoxypropyltin(IV) has been prepared and its structures in different solutions and in the solid state determined using NMR, IR, CP/MAS NMR, ESI MS and X-ray diffraction techniques, respectively. The structure is similar in solution and in the solid state, not intra- or inter-molecular attack of ligand oxygen donor atom to the tin centre was observed. Monoorganotin(IV) compound / Structure elucidation / O-ligand / NMR study / Diethyldithiocarbamate / Electrospray ionization mass spectrometry / X-ray diffraction
eng Structural Study of Tris(N,N-diethyldithiocarbamato-S,S')-3-methoxypropyltin(IV). Searching for Hypercoordinated Monoorganotin(IV) Species Tris(N,N-diethyldithiocarbamato-S,S')-3-methoxypropyltin(IV) has been prepared and its structures in different solutions and in the solid state determined using NMR, IR, CP/MAS NMR, ESI MS and X-ray diffraction techniques, respectively. The structure is similar in solution and in the solid state, not intra- or inter-molecular attack of ligand oxygen donor atom to the tin centre was observed. Monoorganotin(IV) compound / Structure elucidation / O-ligand / NMR study / Diethyldithiocarbamate / Electrospray ionization mass spectrometry / X-ray diffraction