Publication detail

New Aspects of Impact Reactivity of Polynitro Compunds. Part IV. Allocation of Polynitro Compounds on the Basis of their Impact Sensitivities.

Authors: Zeman Svatopluk

Year: 2003

Type of publication: článek v odborném periodiku

Name of source: Propellants Explosives Pyrotechnics

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 308-313

Titles:

Language	Name	Abstract	Keywords
cze			impact sensitivity, polynitro compounds
eng	New Aspects of Impact Reactivity of Polynitro Compunds. Part IV. Allocation of Polynitro Compounds on the Basis of their Impact Sensitivities.	A linear relationship has been found between the drop energies of impact sensitivity detected by sound and the drop energies of ?the first reaction? for 28 polynitro compounds. In the sense of this relationship, the compounds studied fall into three classes. The reason of the said diversification lies in the decomposition reaction rate at the temperature of beginning of their thermolysis. It is stated that some relationship exists between vibrational excitation by impact, on the one hand, and thermal activation of the molecules of energetic materials, on the other.	impact sensitivity, polynitro compounds

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