Publication detail

New Aspects of Impact Reactivity of Polynitro Compunds. Part III. Impact Sensitivity as Function of the Intermolecular Interactions

Authors: Zeman Svatopluk | Krupka Miloslav

Year: 2003

Type of publication: článek v odborném periodiku

Name of source: Propellants Explosives Pyrotechnics

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 301-307

Titles:

Language	Name	Abstract	Keywords
cze			impact sensitivity, heat of fusion, heat of sublimation, polynitro compounds
eng	New Aspects of Impact Reactivity of Polynitro Compunds. Part III. Impact Sensitivity as Function of the Intermolecular Interactions	Published data of impact sensitivity of 33 polynitro compounds detected by sound were expressed as the drop energy, Edr, required for 50 percent initiation probability. A logarithmic relationship has been found between the Edr values and heats of fusion of the said compounds. The relationship has been found to be in accordance with the idea of the role of plastic deformations of crystal played in the initiation of energetic materials by impact and shock. An analogous application of heats of sublimation has not given convincing results.	impact sensitivity, heat of fusion, heat of sublimation, polynitro compounds

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