Publication detail

Physico-chemical aspects of renewal of the electrodes based on mercury or amalgams

Authors: Novotný Ladislav | Polášková Petra

Year: 2008

Type of publication: článek ve sborníku

Name of source: Sborník příspěvků VIII. Pracovní setkání fyzikálních chemiků a elektrochemiků

Publisher name: Masarykova univerzita

Place: Brno

Page from-to: 114-115

Titles:

Language	Name	Abstract	Keywords
cze	Fyzikálně-chemické aspekty obnovování elektrod na bázi rtuti nebo amalgamů	Kombinace mechanického a čistě elektrochemického obnovování povrchu elektrody HMDE je dobře využitelná pro mnoho elektroanalytických i fyzikálně-chemických aplikací.	elektrochemicky obnovované elektrody; rtuť, amalgamy
eng	Physico-chemical aspects of renewal of the electrodes based on mercury or amalgams	Electrodes based on mercury or amalgams represent a very useful tool for voltammetric trace analysis as well as study of bioactive species. Recent development in the field of stationary mercury-based electrodes has brought suggestion of numerous new types of useful designs and applications concerning, e.g., the miniaturized electromechanically renewed hanging (stationary) mercury drop electrodes HMDE/SMDE and the mercury modified solid amalgam (incl. composite amalgam and plastic-tip or glass-tip) electrodes. In principal an electro-chemical renewal of the HMDE-surface could eliminate a respective mechanical irreproducibility of its size. Therefore, a combination of the mechanical and purely electrochemical renewal of the electrode surface of HMDE seems to be useful for many electroanalytical applications. It is supported by the adequate physico-chemical reasons and interpretation of corresponding interfacial behavior of present species.	electrochemically renewed electrodes; mercury, amalgams

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