Publication detail

Comparative Studies of Diphenyl-Diketo-Pyrrolopyrrole Derivatives for Electroluminescence Applications

Authors: Vala M | Weiter M | Vyňuchal Jan | Toman P | Luňák Stanislav

Year: 2008

Type of publication: článek v odborném periodiku

Name of source: Journal of Fluorescence

Publisher name: Springer

Page from-to: 1181-1186

Titles:

Language	Name	Abstract	Keywords
cze	Srovnávací studie difenyl-diketo-pyrrolopyrrol derivátů pro elektroluminiscenční aplikace	Srovnávací studie difenyl-diketo-pyrrolopyrrol derivátů pro elektroluminiscenční aplikace
eng	Comparative Studies of Diphenyl-Diketo-Pyrrolopyrrole Derivatives for Electroluminescence Applications	Four different derivatives of diphenyl-diketo-pyrrolopyrrole (DPP) with alkyl side groups were synthesized to increase their solubility. Quantum chemical calculations revealed that the substitution influenced molecular geometry and subsequently modified absorption and photoluminescence spectra. The theoretical results were confirmed by experimental characterization. With increasing phenyl torsion the vibrational structure was less pronounced and larger Stokes shift was observed. Simultaneously, the molar absorption coefficient decreased as the deformation increased. On the other hand, the measured fluorescence quantum yields were modified only slightly. This indicates the possibility to prepare soluble derivatives without loss of quantum yields and to use these materials for construction of efficient and stable electroluminescent devices. Furthermore, the electroluminescence of the thin layer devices based on the soluble low molecular DPPs were characterized and discussed.	Diphenyl-diketo-pyrrolopyrrole;Organic light emitting diodes - OLED;Electroluminescence

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