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Tribromo(eta-5-1,2,3-trimethylcyclopentadienyl)titanium(IV)
Authors: Erben Milan | Císařová Ivana | Vinklárek Jaromír | Pavlišta Martin
Year: 2004
Type of publication: článek v odborném periodiku
Name of source: Acta Crystallographica Section E - Structure Reports Online
Publisher name: International Union of Crystallography
Page from-to: 1183-1184
Titles:
Language Name Abstract Keywords
cze Tribromo(eta-5-1,2,3-trimethylcyclopentadienyl)titanium(IV) The crystal structure of the title compound, [Ti(Me3Cp)Br3], where Me3Cp is 1,2,3-trimethylcyclopentadienyl (C8H11), was determined. The molecule has typical piano-stool structure in which one \h^5^-bonded trimethylcyclopentadienyl ring and three bromide ligands occupy the pseudotetrahedral coordination sites around the titanium(IV) centre.The Ti-ring distance is 2.0162(16) A. crystal structure, half-sandwich, trimethylcyclopentadienyl
eng Tribromo(eta-5-1,2,3-trimethylcyclopentadienyl)titanium(IV) The crystal structure of the title compound, [Ti(Me3Cp)Br3], where Me3Cp is 1,2,3-trimethylcyclopentadienyl (C8H11), was determined. The molecule has typical piano-stool structure in which one \h^5^-bonded trimethylcyclopentadienyl ring and three bromide ligands occupy the pseudotetrahedral coordination sites around the titanium(IV) centre.The Ti-ring distance is 2.0162(16) A. crystal structure, half-sandwich, trimethylcyclopentadienyl