Publication detail

Reactivity of di-n-butyl-dicyclopentadienylzirconium towards amido stabilized stannylenes

Authors: Bareš Josef | Padělková Zdeňka | Meunier Philippe | Pirio Nadine | Růžička Aleš

Year: 2009

Type of publication: článek v odborném periodiku

Name of source: Journal of Organometallic Chemistry

Page from-to: 1263-1265

Titles:

Language	Name	Abstract	Keywords
cze	Reaktivita di-n-butyl-dicyclopentadienylzirconia a dále amidostabilizovaných stannylenů	Reakce Sn[H(3)iPr(2)-2,6)(SiMe3)](2) a [{Sn)H(3)iPr(2)-2,6)(SiMe3)(mu-Cl)(2)] s di-n- butyl- dicyclopentadienylzirconiem probíhá za vzniku trimetallického karbenu- jako komplexu {[(3)iPr(2)-2,6)(SiMe3)] (n - Bu)Sn}(2)Cp2Zr. Oxidace {[(3)iPr(2)-2,6)(SiMe3)](n-Bu)Sn}(2)Cp2Zr kyslíkem dává pětičlenné dioxadistannazirconiové cyklické komplexy {[(3)iPr(2)-2,6)(SiMe3)](n-Bu)Sn}(2)O2Cp2Zr.	cín;stanylen
eng	Reactivity of di-n-butyl-dicyclopentadienylzirconium towards amido stabilized stannylenes	Reaction of Sn[(N(C(6)H(3)iPr(2)-2,6)(SiMe3)](2) and [{Sn(N(C(6)H(3)iPr(2)-2,6)(SiMe3)(mu-Cl)(2)] with di-n-butyl-dicyclopentadienylzirconium yielded the trimetallic a carbene-like complex {[(N(C(6)H(3)iPr(2)-2,6)(SiMe3)] (n-Bu)Sn}(2)Cp2Zr. The oxidation of {[(N(C(6)H(3)iPr(2)-2,6)(SiMe3)](n-Bu)Sn}(2)Cp2Zr by oxygen gives the five-membered dioxadistannazirconacyclic complex {[(N(C(6)H(3)iPr(2)-2,6)(SiMe3)](n-Bu)Sn}(2)O2Cp2Zr	tin;stannylenes

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