Publication detail

Evidence for the formation of isothiocyanate during sulfurisation of phosphines and phosphites using xanthane hydride

Authors: Hanusek Jiří | Russell Mark | Laws Andrew | Page Michael

Year: 2007

Type of publication: článek v odborném periodiku

Name of source: Tetrahedron Letters

Publisher name: Pergamon-Elsevier Science Ltd.

Place: Oxford

Page from-to: 417-419

Titles:

Language	Name	Abstract	Keywords
cze	Důkaz pro tvorbu isothiokyanátu během sulfurizace fosfinů a fosfitů xanthan hydridem	Navzdory předešlým článkům sulfurizace trifenylfosfinů a trialkyl fosfitů 3-amino-1,2,4-dithiazol-5-thionem (xanthan hydridem) neposkytuje sirouhlík a kyanamid jako vedlejší reakční produkty ale tvoří se nestabilní thiokarbamoyl isothiokyanát, který byl zachycen reakcí s nukleofily.	thiokarbamoylisothiokyanát, sulfurizace, fosfiny, fosfity, xanthan hydrid
eng	Evidence for the formation of isothiocyanate during sulfurisation of phosphines and phosphites using xanthane hydride	Contrary to a previous report, the sulfurisation of triphenylphosphines and trialkyl phosphites by 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride) does not yield carbon disulfide and cyanamide as the additional reaction products but unstable thiocarbamoyl isothiocyanate which has been trapped with nucleophiles.	thiocarbamoylisothiocyanate, sulfurisation, phosphines, phosphites, xanthane hydride

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