Publication detail

Palladium and Molybdenum Complexes of the Heteroleptic Organostannylene [2,6-(Me2NCH2)2C6H3]SnCl

Year: 2009

Type of publication: článek v odborném periodiku

Name of source: Organometallics

Publisher name: American Chemical Society

Place: Washington

Page from-to: 4778-4782

Titles:

Language	Name	Abstract	Keywords
cze	Palladnaté a molybdenové komplexy stanylenu [2,6-(Me2NCH2)2C6H3]SnCl	Synteza a struktura komplexů stanylenu [2,6-(Me2NCH2)2C6H3]SnCl s prechodnymi kovy vedla k synteze komplexů {[2,6-(Me2NCH2)2C6H3]SnCl}(C5H5)(CO)2MoCl (6) a {[2,6-(Me2NCH2) 2C6H3]Sn(OAc)}Pd(Cl)[2-Me2NCH2)C6H4] (7).	stanylen;pincer ligandy;přechodné kovy
eng	Palladium and Molybdenum Complexes of the Heteroleptic Organostannylene [2,6-(Me2NCH2)2C6H3]SnCl	The synthesis and molecular structures are reported for the transition metal heteroleptic organostannylene complexes {[2,6-(Me2NCH2)2C6H3]SnCl}(C5H5)(CO)2MoCl (6) and {[2,6-(Me2NCH2) 2C6H3]Sn(OAc)}Pd(Cl)[2-Me2NCH2)C6H4] (7). It is shown that the intramolecularly coordinated heteroleptic organostannylene [2,6-(Me2NCH2)2C6H3]SnCl undergoes a redox-type reaction with Pd(PPh3)4 to give cis-[2,6-(Me2NCH2)2C6H3]SnCl}2PdCl2.	stannylene;pincer ligand;transition metals

Search