Publication detail

Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O]: An N -> Sn Coordinated Stannonic Acid

Authors: Bouška Marek | Dostál Libor | Jirásko Robert | Růžička Aleš | Jambor Roman

Year: 2009

Type of publication: článek v odborném periodiku

Name of source: Organometallics

Publisher name: American Chemical Society

Place: Washington

Page from-to: 4258-4261

Titles:

Language	Name	Abstract	Keywords
cze	Syntéza [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O]: N -> Sn koordinovaná cíničitá kyselina	Hydrolýzou RSn(H2O)(O2CCF3)3 došlo k přípravě první intramolekulárně koordinované cíničité kyseliny RSn(OH)O]6 (3) (R je N, C,N- ligand [2,6-(Me2NCH2)2C6H3]-). Byla studována struktura a mechanismus přípravy této sloučeniny.
eng	Synthesis of [{2,6-(Me2NCH2)(2)C6H3}Sn(OH)O]: An N -> Sn Coordinated Stannonic Acid	The discovery of the possible hydrolytic mechanism of the monoorganotin(IV) compound RSn(H2O)(O2CCF3)3 (2) resulted in the preparation of the first intramolecularly coordinated stannonic acid, [RSn(OH)O]6 (3) (R is the N,C,N-pincer ligand [2,6-(Me2NCH2)2C6H3]-). The presence of N-Sn coordination prevents the formation of additional Sn-O interactions and results in the stabilization of the unique centrosymmetric {Sn6O12} core in 3.	organotin, chelating ligand, X ray analysis

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