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Selective Catalytic Reduction of NOx Over Nano-Sized Gold Catalysts Supported on Alumina and Titania and Over Bimetallic Gold?Silver Catalysts Supported on Alumina
Authors: Arve K. | Adam Jiří | Simakova O. | Čapek Libor | Eränen K. | Murzin D. Yu.
Year: 2009
Type of publication: článek v odborném periodiku
Name of source: Topics in Catalysis
Publisher name: Springer
Page from-to: 1762-1765
Titles:
Language Name Abstract Keywords
cze Selektivní katalytická redukce NOx na katalytických systémech na Ag-, Au- a AgAu-Al2O3 a -TiO2 Byla studována redukce NO na N2 pomocí dekanu v přebytku kyslíku a to na katalyzátorech na bázi zlata, stříbra a duálních katalyzátorů na bázi stříbra a zlata nanesených na anorganických nosičích Al2O3 a TiO2. Katalyzátory byly charakterizovány pomocí EDXS, adsorpce dusíku, UV-Vis a TEM. HC-SCR;stříbro;zlato;alumina;TiO2
eng Selective Catalytic Reduction of NOx Over Nano-Sized Gold Catalysts Supported on Alumina and Titania and Over Bimetallic Gold?Silver Catalysts Supported on Alumina The reduction of NO with octane under lean conditions was examined over gold supported on alumina and titania and over alumina supported bimetallic gold-silver catalysts. The silver loading was either 1.2 or 1.9 wt% whereas 0.3, 1 or 5 wt% gold was used. The catalysts were characterized by means of EDXS, N-2-adsortion, UV-Vis and TEM to correlate recorded results with different preparation methods. UV-Vis measurements indicated that gold was present in the form of fine Au particles, single Au ions and small (Au)(n)(delta+) clusters on the catalysts and silver was mainly present in the form of single Ag ions. The highest NO to N-2 reduction activity was recorded over the 0.3Au-Al2O3 catalyst. The Au-TiO2 catalysts did not result in significant NO to N-2 reduction. HC-SCR;Gold;Silver;Aluminium oxide;Titanium oxide