Publication detail

Reaction of methylnitramine and ethylenedinitramine with dihalogenmethanes

Authors: Jalový Zdeněk | Foud Jaromír

Year: 2009

Type of publication: článek ve sborníku

Name of source: Proceedings of the 12th Seminar on New Trends in Research of Energetic Materials

Publisher name: Univerzita Pardubice

Place: Pardubice

Page from-to: 563-566

Titles:

Language	Name	Abstract	Keywords
cze	Reakce methylnitraminu a ethylendinitraminu s dihalogenmethany	Methylnitramin (1) reaguje s dibromomethanem (2a) nebo bromochloromethanem (2b)za přítomnosti uhličitanu draselného. Vzniká 2,4-dinitro-2,4-diazapentan (3) ve výtěžcích 28 % a 23 %.. Pokud ethylendinitramin (4) reaguje s dihalogenmethanem za stejných podmínek, vzniká 1,3 dinitroimidazolidine (5), avšak výtěžky jsou podstatně nižší 5.	2,4-dinitro-2,4-diazapentan;dibromomethan;bromochloromethan 1,3-initroimidazolidin
eng	Reaction of methylnitramine and ethylenedinitramine with dihalogenmethanes	Methylnitramine (1) reacts with dibromomethane (2a) or bromochloromethane (2b) in the presence of potassium carbonate as a base to produce 2,4-dinitro-2,4-diazapentane (3) in the yields of 28 % and 23 %, respectively. When ethylenedinitramine (4) reacts with dihalogenmethanes at the same conditions, 1,3 dinitroimidazolidine (5) is formed. However, the yield of 5 is considerably lower than in the case of 5.	2,4-dinitro-2,4-diazapentane;dibromomethane;bromochloromethane 1,3- dinitroimidazolidine

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