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Structure of C,N-chelated nButyltin(IV) fluorides and their use as fluorating agents of some chlorosilanes, chlorophosphine and metal halides.
Authors: Švec Petr | Novák Petr | Nádvorník Milan | Padělková Zdeňka | Císařová Ivana | Kolářová Lenka | Růžička Aleš | Holeček Jaroslav
Year: 2007
Type of publication: článek v odborném periodiku
Name of source: Journal of Fluorine Chemistry
Publisher name: Elsevier Science SA
Place: Lausanne
Page from-to: 1390-1395
Titles:
Language Name Abstract Keywords
cze Structure of C,N-chelated nButyltin(IV) fluorides and their use as fluorating agents of some chlorosilanes, chlorophosphine and metal halides. The tin atom in the solid-state structure of {2-[(CH3)2NCH2]C6H4}nBu2SnF is five coordinated with carbon atoms in equatorial and fluorine and nitrogen atoms in axial positions. The fluorination of {2-[(CH3)2NCH2]C6H4}nBuSnCl2 is described by NMR methods. The successful attempts to fluorinate various chlorosilanes, chlorophosphine and metal halides are also reported.
eng Structure of C,N-chelated nButyltin(IV) fluorides and their use as fluorating agents of some chlorosilanes, chlorophosphine and metal halides. The tin atom in the solid-state structure of {2-[(CH3)2NCH2]C6H4}nBu2SnF is five coordinated with carbon atoms in equatorial and fluorine and nitrogen atoms in axial positions. The fluorination of {2-[(CH3)2NCH2]C6H4}nBuSnCl2 is described by NMR methods. The successful attempts to fluorinate various chlorosilanes, chlorophosphine and metal halides are also reported. Organotin(IV) fluorides; C,N-ligand; Structure