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Synthesis, Characterization and Structure of Metallocene Dicyanoamide Complexes
Authors: Honzíček Jan | Erben Milan | Císařová Ivana | Vinklárek Jaromír
Year: 2005
Type of publication: článek v odborném periodiku
Name of source: Inorganica Chimica Acta
Publisher name: Elsevier Science SA
Place: Lausanne
Page from-to: 814-819
Titles:
Language Name Abstract Keywords
cze Synthesis, Characterization and Structure of Metallocene Dicyanoamide Complexes The complexes [Cp2Ti(NCNCN)]2O and Cp2V(NCNCN)2 have been prepared from corresponding metallocene dichlorides by reaction with sodium dicyanoamide in aqueous solution. The X-ray structure analyses of both complexes confirmed monodentate coordination of dicyanoamide ligand via terminate cyano nitrogen atom titanocene, vanadocene, pseudohalide, dicyanoamide complexes, X-ray structure, NMR spectroscopy, EPR spectroscopy
eng Synthesis, Characterization and Structure of Metallocene Dicyanoamide Complexes The complexes [Cp2Ti(NCNCN)]2O and Cp2V(NCNCN)2 have been prepared from corresponding metallocene dichlorides by reaction with sodium dicyanoamide in aqueous solution. The X-ray structure analyses of both complexes confirmed monodentate coordination of dicyanoamide ligand via terminate cyano nitrogen atom titanocene, vanadocene, pseudohalide, dicyanoamide complexes, X-ray structure, NMR spectroscopy, EPR spectroscopy