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Raman Spectroscopic Evidence for Bent Metallocene Fragments Cp2M
Authors: Pavlišta Martin | Bína Radim | Černošek Zdeněk | Erben Milan | Vinklárek Jaromír | Pavlík Ivan
Year: 2005
Type of publication: článek v odborném periodiku
Name of source: Applied Organometallic Chemistry
Publisher name: John Wiley & Sons Ltd.
Place: Chichester
Page from-to: 90-93
Titles:
Language Name Abstract Keywords
cze Důkaz metalocenových fragmentů Cp2M pomocí Ramanovy spektroskopie Ramanovu spektroskopii v pevné fázi i v roztoku lze použít pro jednoznačnou detekci metallocenových fragmentů Cp2M v různých molekulách. bent metallocene fragment; Raman spectroscopy; titanocene dichloride; amino acid complexes
eng Raman Spectroscopic Evidence for Bent Metallocene Fragments Cp2M Raman spectroscopy was used as a very simple and convenient tool for the detection of bent metallocene fragments [M(Cp)2]2+ (Cp = n(5)-cyclopentadienyl ring; M = early transition metal) both in solid state and in solution. The rules were formulated and tested on the group of titanium complexes containing one or two 5-bonded cyclopentadienyl rings, as well as on a series of model alfa-amino acid complexes of antitumour active titanocene and vanadocene dichlorides. bent metallocene fragment;Raman spectroscopy;titanocene dichloride;amino acid complexes