Publication detail

{(eta-5,kappa-N)-[( tert-Butylamido)dimethylsilyl]cyclopentadienyl}dichlorotitanium(IV)

Authors: Erben Milan | Císařová Ivana | Vinklárek Jaromír | Dušek Michal

Year: 2005

Type of publication: článek v odborném periodiku

Name of source: Acta Crystallographica Section E - Structure Reports Online

Publisher name: International Union of Crystallography

Page from-to: M50-M51

Titles:

Language	Name	Abstract	Keywords
cze	{(eta-5,kappa-N)-[( tert-Butylamido)dimethylsilyl]cyclopentadienyl}dichlorotitanium(IV)	Krystalová struktura sloučeniny [Ti(C11H19NSi)Cl2] byla stanovena jako součást zkoumání titanových komplexů	metallocene, constrained geometry complex, crystal structure
eng	{(eta-5,kappa-N)-[( tert-Butylamido)dimethylsilyl]cyclopentadienyl}dichlorotitanium(IV)	The crystal structure of the title compound, [Ti(C11H19NSi)Cl2], has been determined as part of a broad investigation of half-sandwich titanium complexes. Titanium has a pseudotetrahedral coordination formed by two Cl atoms , the N atom of the N-tert-butyl group and the silyl-substituted Cp ligand. The tert-butyl group was found to be disordered.	metallocene, constrained geometry complex, crystal structure

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