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Acetonitrilechlorotris(5-cyclopentadienyl)vanadium(IV) tetrachloroferrate(III)
Authors: Honzíček Jan | Císařová Ivana | Vinklárek Jaromír
Year: 2005
Type of publication: článek v odborném periodiku
Name of source: Acta Crystallographica Section E - Structure Reports Online
Publisher name: International Union of Crystallography
Page from-to: 159-161
Titles:
Language Name Abstract Keywords
cze Acetonitrilechlorotris(5-cyclopentadienyl)vanadium(IV) tetrachloroferrate(III) The structure of the title compound, [V(C5H5)(2)Cl(C2H3N)][FeCl4], a potential spermicidally active species, has been determined. This compound has a typical bent metallocene structure, in which two eta(5)-bonded cyclopentadienyl rings, an N-coordinated acetonitrile molecule and a Cl ligand occupy tetrahedral positions around the V-IV atom. The V-N bond length was found to be 2.087 (2) Angstrom. COMPLEXES
eng Acetonitrilechlorotris(5-cyclopentadienyl)vanadium(IV) tetrachloroferrate(III) The structure of the title compound, [V(C5H5)(2)Cl(C2H3N)][FeCl4], a potential spermicidally active species, has been determined. This compound has a typical bent metallocene structure, in which two eta(5)-bonded cyclopentadienyl rings, an N-coordinated acetonitrile molecule and a Cl ligand occupy tetrahedral positions around the V-IV atom. The V-N bond length was found to be 2.087 (2) Angstrom. COMPLEXES