Publication detail

Role of O,C,O-ligand in a New Coordidination Mode of Organotin Compounds to 2-mercapto-1-imidaziol. Stabilization of its thione form

Authors: Martincová Jana | Dostál Libor | Taraba Jan | Jambor Roman

Year: 2007

Type of publication: článek v odborném periodiku

Name of source: Journal of Organometallic Chemistry

Page from-to: 908-911

Titles:

Language	Name	Abstract	Keywords
cze	Role OCO chelátujícího ligandu ve stabilizaci thionové formy	Byla připravena organocíničitá sloučenina obsahující YCY chelátující ligand díky nemuž byla stabilizována thionová forma imidazolu
eng	Role of O,C,O-ligand in a New Coordidination Mode of Organotin Compounds to 2-mercapto-1-imidaziol. Stabilization of its thione form	The reaction of the organotin compound [Ph2LSn]+ [OTf]- (1), (L(O,C,O) = 2,6-(t-BuOCH2)2C6H3), with the sodium salt Na(mimt), mimt = 1-methylimidazole-2-thiolate, resulted in the isolation of Ph2LSn(mimt) (2), where the polar group (mimt) has been stabilized as the thione-tautomeric form by the triorganotin fragment Ph2LSn. Product 2 was characterized by 1H, 13C and 119Sn NMR and IR spectroscopy, ESI/MS, elemental analyses and X-ray diffraction	organotin compounds, YCY chelating ligands,

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