Publication detail

Steric Effects in Isolated Molecules: Gas-Phase Basicity of Methyl-Substituted Acetophenones.

Authors: Böhm Stanislav | Gal Jean-Francois | Maria Pierre-Charles | Kulhánek Jiří | Exner Otto

Year: 2005

Type of publication: článek v odborném periodiku

Name of source: European Journal of Organic Chemistry

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 2580-2588

Titles:

Language	Name	Abstract	Keywords
cze	Sterický efekt v izolované molekule: bazicita v plynné fázi methylsubstituovaných acetofenonů.	Byly vypočítány energie 14 methylsubstituovaných acetofenonů a jejich protonovaných forem. Byla změřena jejich bazicita v plynné fázi. Protonovaná forma existuje ve dvou konfiguracích lišících se pozicí vodíku.
eng	Steric Effects in Isolated Molecules: Gas-Phase Basicity of Methyl-Substituted Acetophenones.	The energies of 14 methyl-substituted acetophenones and their protonated forms were calculated. The gas-phase basicities were measured. The protonated forms exist in two configurations differing in the position of the hydrogen atom.	Density functional calculation, gas-phase basicity, isodesmic reaction, steric effects

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