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PalladiumII Complexes of the (N,C,N)SnCl Stannylene
Authors: Martincová Jana | Dostál Libor | Růžička Aleš | Taraba Jan | Jambor Roman
Year: 2007
Type of publication: článek v odborném periodiku
Name of source: Organometallics
Publisher name: American Chemical Society
Place: Washington
Page from-to: 4102-4104
Titles:
Language Name Abstract Keywords
cze Palladnaté komplexy (N,C,N)SnCl Reakcí (N,C,N)SnCl s paladnatými komplexy vznikly komplexy obsahující Sn-Pd vazbu.
eng PalladiumII Complexes of the (N,C,N)SnCl Stannylene The reactions of heteroleptic stannylene (N,C,N)SnCl (1), where N,C,N is an abbreViation for N,C,N-chelate 2,6-(Me2- NCH2)2C6H3, with selected palladium complexes resulted in new SnII-PdII complexes in which 1 itself acts as a 2e-donor ligand, resulting in a Cl-PdII-SnII-Cl structural motif, instead of a PdII-SnII-Cl2, which would be expected in the case of insertion of 1 into a PdII-Cl bond. stannylene, palladium, complexes, NCN-ligand