Publication detail

Dimeric Diorganotin Dications: Structure and Catalytic Activity in Alcohol Acetylation

Authors: Kašná Blanka | Dostál Libor | Císařová Ivana | Jambor Roman

Year: 2007

Type of publication: článek v odborném periodiku

Name of source: Organometallics

Publisher name: American Chemical Society

Place: Washington

Page from-to: 4080-4082

Titles:

Language	Name	Abstract	Keywords
cze	Dimerní Diorganocíničitý Dikationt	Byl přiraven Sn2 diorganocíničitý dikationt [Ph(L1)Sn(í-OH)2Sn(L1)Ph]2+(1-CB11H12)- 2 (2), kde L1 is 1-{2,6-(MeOCH2)2C6H3}
eng	Dimeric Diorganotin Dications: Structure and Catalytic Activity in Alcohol Acetylation	We report the stabilization of the Sn2 diorganotin- (IV) dication [Ph(L1)Sn(í-OH)2Sn(L1)Ph]2+(1-CB11H12)- 2 (2), where L1 is 1-{2,6-(MeOCH2)2C6H3}, which in contrast to the rare analogues prepared thus far does not contain a coordinated water molecule. Compound 2 exhibits high catalytic actiVity in the acetylation of alcohols.	hydrolysis, tin cation, YCY ligand

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