Publication detail

The novel organolithium O,C,O-pincer compound

Authors: Jambor Roman | Dostál Libor | Císařová Ivana | Růžička Aleš | Holeček Jaroslav

Year: 2005

Type of publication: článek v odborném periodiku

Name of source: Inorganica Chimica Acta

Publisher name: Elsevier Science SA

Place: Lausanne

Page from-to: 2422-2426

Titles:

Language	Name	Abstract	Keywords
cze	Organolithná sloučenina obsahující O,C,O-chelátující ligand	Byla připravena organolithná sloučenina obsahující O,C,O-chelátující ligand.
eng	The novel organolithium O,C,O-pincer compound	The preparation and characterization of organolithium O,C,O-pincer compound [2,6-(tBuOCH2)2C6H3]-Li (1) is described. The X-ray diffraction techniques revealed the dimeric structure of 1 consisting of two lithium atoms Li(1) and Li(2) and two monoanionic chelating aryl ligands in the solid state, where each lithium atom is coordinated by two oxygen atoms of two different ligands. The NMR spectroscopy and cryoscopy measurements established monomer-dimer equilibrium of 1 in concentrated solutions of non-coordinated solvents, while the diluted solutions of 1 consists of monomer only.	lithium;O ligand;X ray diffraction

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