Publication detail

Difluoro(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV)

Authors: Erben Milan | Císařová Ivana | Vinklárek Jaromír | Picka Michal

Year: 2005

Type of publication: článek v odborném periodiku

Name of source: Acta Crystallographica Section E - Structure Reports Online

Publisher name: International Union of Crystallography

Page from-to: m1266-m1268

Titles:

Language	Name	Abstract	Keywords
cze	Difluoro(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV)	In the title compound, [Ti(C13H14)F2], the coordination polyhedron around the Ti atom is a distorted tetrahedron defined by the centroids of the cyclopentadienyl rings and the two F atoms. The Ti?ring centroid (Cg) distances are 2.0558 (7) and 2.0567 (8) A° . The presence of a short carbon bridge linking the cyclopentadienyl rings constrains the Cg? Ti?Cg angle to a value of 121.50 (3)DEG.	ansa-metalloceny, titan, mlekulová struktura
eng	Difluoro(eta5,eta5-propane-2,2-diyldicyclopentadienyl)titanium(IV)	In the title compound, [Ti(C13H14)F2], the coordination polyhedron around the Ti atom is a distorted tetrahedron defined by the centroids of the cyclopentadienyl rings and the two F atoms. The Ti?ring centroid (Cg) distances are 2.0558 (7) and 2.0567 (8) A° . The presence of a short carbon bridge linking the cyclopentadienyl rings constrains the Cg? Ti?Cg angle to a value of 121.50 (3)DEG.	ansa-metallocenes, titanium, X-ray

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