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Dibromobis[2-(N,N-dimethylaminomethyl)phenyl]tin(IV)
Authors: Padělková Zdeňka | Císařová Ivana | Růžička Aleš
Year: 2005
Type of publication: článek v odborném periodiku
Name of source: Acta Crystallographica Section E - Structure Reports Online
Publisher name: International Union of Crystallography
Page from-to: 2691-2693
Titles:
Language Name Abstract Keywords
cze Dibromobis[2-(N,N-dimethylaminomethyl)phenyl]tin(IV) In the crystal structure of the title compound, [SnBr2-( C9H12N)(2)], the Sn atom is pseudo-octahedrally coordinated as a result of the C, N-chelation by the 2-( N,N-dimethylaminomethyl) phenyl groups and two cis-bonded bromides. The C atoms bonded to Sn are in trans positions [C-Sn-C = 156.7 (2)degrees] and the coordinated N atoms are bonded in a cis fashion [N-Sn = 2.581 (5) and 2.600 (5) angstrom; N-Sn-N = 103.88 (16)degrees].
eng Dibromobis[2-(N,N-dimethylaminomethyl)phenyl]tin(IV) In the crystal structure of the title compound, [SnBr2-( C9H12N)(2)], the Sn atom is pseudo-octahedrally coordinated as a result of the C, N-chelation by the 2-( N,N-dimethylaminomethyl) phenyl groups and two cis-bonded bromides. The C atoms bonded to Sn are in trans positions [C-Sn-C = 156.7 (2)degrees] and the coordinated N atoms are bonded in a cis fashion [N-Sn = 2.581 (5) and 2.600 (5) angstrom; N-Sn-N = 103.88 (16)degrees]. CRYSTAL-STRUCTURES; CHEMISTRY; HALIDES