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Publication detail

N-type to p-type crossover in quaternary BixSbyPbzSe3 single crystals
Authors: Kašparová Jana | Drašar Čestmír | Krejčová Anna | Beneš Ludvík | Lošťák Petr | Chen Wei | Zhou Zhenhua | Uher C
Year: 2005
Type of publication: článek v odborném periodiku
Name of source: Journal of Applied Physics
Publisher name: American Institute of Physics
Place: Melville
Page from-to: 103720/1-103720/5
Titles:
Language Name Abstract Keywords
cze Změna typu elektrické vodivosti v kvaternárních monokrystalech BixSbyPbzSe3 Práce popisuje způsob přípravy p-typového monokrystalického Bi2Se3 s použitím dvojitého dopování antimonem a olovem.
eng N-type to p-type crossover in quaternary BixSbyPbzSe3 single crystals We report on the preparation and some physical properties of a new type quaternary system based on Bi2Se3 co-doped with Sb and Pb. Single crystal samples were prepared using the Bridgman technique and were characterized by measurements of the lattice parameters, electrical resistivity, Hall coefficient, Seebeck coefficient and thermal conductivity. Atomic emission spectroscopy was used to find the concentration profiles of Sb and Pb along the single-crystalline ingots. Progressive co-doping of the Bi2Se3 crystal lattice with Sb and Pb leads to a crossover of the initially n-type conduction to that of the p-type. It is assumed that both Sb and Pb enter the Bi-sublattice. Physical properties as well as the change in the dominant carrier type are discussed in the context of the concentration of various point defects. A new complex defect is introduced to account for some features of the data. Crystals of tetradymite structure, Quaternary crystals, Transport coefficients, Point defects