Publication detail

On the reaction pathway in the oxidative dehydrogenation of propane with nitrous oxide over Fe-MFI catalyst

Authors: Bulánek Roman | Adam Jan | Částek František

Year: 2005

Type of publication: článek ve sborníku

Name of source: Proceedings 7th AIZ Conferece on Zeolite Science and Technology joint with 1st Czech-Italian Workshop on Catalysis and Zeolites.

Publisher name: G. Giordano

Place: Calabria

Page from-to: 47-50

Titles:

Language	Name	Abstract	Keywords
cze	xx	Oxidace propanu pomocí N2O byla studována za účelem zjištění reakčního mechanismu vzniku hlavních produktů. Předpokládaným adsorbovaným intermediátem by mohly být pravděpodobně: i) 1-propyloxy nebo allyloxy částice jako prekurzory propanalu a ii) 2-propyloxy částice jako prekurzor acetonu nebo propenu.
eng	On the reaction pathway in the oxidative dehydrogenation of propane with nitrous oxide over Fe-MFI catalyst	Oxidation of propane with N2O over Fe-MFI zeolites with 2500 ppm of iron was investigated in order to analyze the reaction way. A parallel-consecutive reaction scheme was suggested for conversion of propane to propene and propanal and acetone. The reaction intermediates to oxygenate products, which necessarily involves an oxygenation step, should be probably: i) the 1-propyloxy or allyloxy species as precursorof propanal and ii) 2- propyloxy species as precursor of acetone and propene.	propane, dehydrogenation, nitrous oxide

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