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Structural study of bis(triorganotin(IV)) esters of 4-ketopimelic acid

Authors: Chalupa Jan | Handlíř Karel | Císařová Ivana | Jirásko Robert | Brus Jiří | Lyčka Antonín | Růžička Aleš | Holeček Jaroslav

Year: 2006

Type of publication: článek v odborném periodiku

Name of source: Journal of Organometallic Chemistry

Page from-to: 2631-2640

Titles:

Language	Name	Abstract	Keywords
cze	Structural study of bis(triorganotin(IV)) esters of 4-ketopimelic acid	The set of six bis(triorganotin(IV)) esters of 4-ketopimelic acid was prepared. Their structures were studied using IR, NMR and X-ray crystallographic (cyclohexyl and ethyl derivatives) techniques both in solution and the solid state. Five of these compounds are polymeric in the solid state and depolymerise upon dissolving in non-coordinating and/or addition of coordinating solvent to monomeric species with four-coordinated tin atom or complexes with donor solvent with five-coordinated tin central atom. The tricyclohexyltin derivative is dimeric in the solid state and monomeric in solution.
eng	Structural study of bis(triorganotin(IV)) esters of 4-ketopimelic acid	The set of six bis(triorganotin(IV)) esters of 4-ketopimelic acid was prepared. Their structures were studied using IR, NMR and X-ray crystallographic (cyclohexyl and ethyl derivatives) techniques both in solution and the solid state. Five of these compounds are polymeric in the solid state and depolymerise upon dissolving in non-coordinating and/or addition of coordinating solvent to monomeric species with four-coordinated tin atom or complexes with donor solvent with five-coordinated tin central atom. The tricyclohexyltin derivative is dimeric in the solid state and monomeric in solution.	Triorganotin(IV) esters; Ketopimelic acid; NMR; X-ray