Publication detail

1-[2-(N,N-dimethylaminomethyl)phenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol

Authors: Erben Milan | Císařová Ivana | Dušek Michal | Vinklárek Jaromír

Year: 2007

Type of publication: článek v odborném periodiku

Name of source: Acta Crystallographica Section E - Structure Reports Online

Publisher name: International Union of Crystallography

Page from-to: o577-o579

Titles:

Language	Name	Abstract	Keywords
cze	1-[2-(N,N-dimethylaminomethyl)fenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol	The crystal structure of the title compound, C38H33NO, shows that the OH group interacts with the N atom of the dimethylamino group via an intramolecular hydrogen bond, resulting in the formation of a seven-membered ring. The presence of this interaction, the poor nucleofugal properties of the hydroxy function and the particularly high steric hindrance decrease the ability of the OH group for substitution by other nucleophiles. The crystal packing exhibits no classical intermolecular hydrogen bonds.	molekulová struktura, vodíková vazba
eng	1-[2-(N,N-dimethylaminomethyl)phenyl]-2,3,4,5-tetraphenylcyclopentadien-1-ol	The crystal structure of the title compound, C38H33NO, shows that the OH group interacts with the N atom of the dimethylamino group via an intramolecular hydrogen bond, resulting in the formation of a seven-membered ring. The presence of this interaction, the poor nucleofugal properties of the hydroxy function and the particularly high steric hindrance decrease the ability of the OH group for substitution by other nucleophiles. The crystal packing exhibits no classical intermolecular hydrogen bonds.	X-ray structure, hydrogen bonding

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