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Publication detail

Ansa-vanadocene complexes with short interannular bridge.
Authors: Honzíček Jan | Paláčková Hana | Císařová Ivana | Vinklárek Jaromír
Year: 2006
Type of publication: článek v odborném periodiku
Name of source: Journal of Organometallic Chemistry
Page from-to: 202-207
Titles:
Language Name Abstract Keywords
cze Ansa-vanadocene complexes with short interannular bridge. The new ansa-vanadocene complexes with short interannular bridge (CH3)2C(C5H4)2VX2 (X = Cl, Br) were prepared, characterized by spectroscopic methods and X-ray structural analysis. It was shown, that connection of cyclopentadienyl rings by dimethylmethane bridge affects the structural parameters. The behavior ansa-vanadocene dichloride in aqueous solution in presence of bio-ligands was studied by EPR spectroscopy. Ansa-metallocene; vanadocene dichloride; X-ray structural analysis; EPR spectroscopy; antitumor agents
eng Ansa-vanadocene complexes with short interannular bridge. The new ansa-vanadocene complexes with short interannular bridge (CH3)2C(C5H4)2VX2 (X = Cl, Br) were prepared, characterized by spectroscopic methods and X-ray structural analysis. It was shown, that connection of cyclopentadienyl rings by dimethylmethane bridge affects the structural parameters. The behavior ansa-vanadocene dichloride in aqueous solution in presence of bio-ligands was studied by EPR spectroscopy. Ansa-metallocene; vanadocene dichloride; X-ray structural analysis; EPR spectroscopy; antitumor agents