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Development of chalcogenide glass photoresists for gray scale lithography
Authors: Kovalskiy Andriy | Vlček Miroslav | Jain Himanshu | Fišerová Alena | Waits Chris | Dubey M
Year: 2006
Type of publication: článek v odborném periodiku
Name of source: Journal of Non-Crystalline Solids
Publisher name: Elsevier Science BV
Place: Amsterdam
Page from-to: 589-594
Titles:
Language Name Abstract Keywords
cze Vývoj fotorezistu na bázi amorfního chalkogenidu pro gray scale litografii Práce se zabývá tvorbou 3D mikrostruktur v anorganických fotorezistech na bázi systému As-S mokrým a suchýmm leptáním. Mokrou cestou byla připravena mikročočková pole s průměrem mikročoček 12 mikronů. Selektivního leptání suchou cestou bylo dosaženo s využitím jevu fotoindukované difuze kovu v binárním systému Ag-As2S3. S využitím metod SEM a XPS byla prokázána segregace Ag na rozhraní exponovaná-neexponovaná vrstva.
eng Development of chalcogenide glass photoresists for gray scale lithography Wet and dry negative etching procedures are evaluated for the fabrication of 3D graded microstructures in As?S based inorganic photoresists. Absorption of light and consequent photostructural changes near the surface layer enhance the chemical resistance of the As?S films. The success of the procedure is demonstrated by fabricating arrays of 12 lm diameter microlenses in a thin As35S65 film using a gray scale Cr mask and wet etching. The selectivity of dry etching is successfully realized by using photodiffusion in Ag?As2S3 bilayer structure. In this case, however, surface roughness or ?grass? is observed after etching. An unexpected segregation of silver is observed at the edges and at the boundary between the exposed and unexposed regions, which is investigated by SEM and XPS. Diffusion and transport; Chalcogenides; Laser?matter interactions; Scanning electron microscope; Photoinduced effects