Publication detail

Vanadyl phosphate intercalated with dimethyl sulfoxide.

Year: 2006

Type of publication: článek v odborném periodiku

Name of source: Journal of Physics and Chemistry of Solids

Publisher name: Pergamon-Elsevier Science Ltd.

Place: Oxford

Page from-to: 956-960

Titles:

Language	Name	Abstract	Keywords
cze	Fosforečnan vanadylu interkalovaný dimethylsulfoxidem.	Interkalát s dimethylsulfoxidem (DMSO) byl připraven náhradou molekul 2-propanolu v odpovídajícím interkalátu molekulami DMSO. Interkalát obsahuje jednu molekulu DMSO na jednu vzorcovou jednotku. Difraktogram obsahuje difrakční čáry dokazující pravidelnou strukturu. Charakter vazeb mezi hostem a hostitelskými vrstvami byl studován pomocí IČ a Ramanovy spektroskopie. Uspořádání molekul DMSO v mezivrstvém prostoru bylo simulováno pomocí pragramového balíku CERIUS v kombinaci s pragramem SUPRAMOL.	interkalát
eng	Vanadyl phosphate intercalated with dimethyl sulfoxide.	The dimethyl sulfoxide (DMSO) intercalate was prepared by replacing 2-propanol molecules in the corresponding VOPO4 intercalate with DMSO. The intercalate contains one DMSO molecule per formula unit. The diffractogram of the intercalate contains diffraction lines giving evidence of a regular structure. The character of the bonding between the quest and the host layers in theDMSO intercalate was studied by infrared and Raman spectroscopies. The arrangement of the DMSO molecules in the interlayer space was simulate using a Cerius 2 software package combined with a Supramol program.	intercalate

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