Publication detail

Structural study on the organoantimony(III) NCN – Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 – Influence of the polar group X

Year: 2010

Type of publication: článek v odborném periodiku

Name of source: Journal of Organometallic Chemistry

Page from-to: 392-397

Titles:

Language	Name	Abstract	Keywords
cze	Strukturální studie intramolekulárně koordinovaných organoantimonitých sloučenin	Byla studována závislost síly intramolekulární interakce N-Sb na typu polárních skupin. Byly také charakterizovány různé druhy koordinačních polyedrů.	Strukturální; studie; intramolekulárně; koordinovaných; organoantimonitých; sloučenin
eng	Structural study on the organoantimony(III) NCN – Chelated compounds [2,6-(Me2NCH2)2C6H3]SbX2 – Influence of the polar group X	It was demonstrated that the behaviour of polar group X in the compounds of the type [2,6-(Me2NCH2)2C6H3]SbX2 has a crucial effect on the geometry around the central antimony atom. The shapes of coordination polyhedron range from a bicapped – trigonal pyramid (X = CH3COO), and a distorted tetragonal pyramid (X = CF3COO) to a ψ-trigonal bipyramid (X = Cl, CB11H12). Even more, an unusual dinuclear ionic complex was prepared and characterized and in this case the structure of the organometallic cation can be described as one apex sharing distorted tetragonal pyramids.	Structural; study; the; organoantimony(III); NCN; Chelated; compounds; [2,6-(Me2NCH2)2C6H3]SbX2; Influence; the; polar; group

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