Publication detail

[{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+¬CB11H12–: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure,

Year: 2010

Type of publication: článek v odborném periodiku

Name of source: European Journal of Inorganic Chemistry

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 902-908

Titles:

Language	Name	Abstract	Keywords
cze	[{2,6-(Me2NCH2)lC6H3(H2O)Sn}W(CO)5]+¬CB11H12–: Aqua Komplex Organocínatého kationtu	Byl připraven komplex [{2,6-(Me2NCH2)lC6H3(H2O)Sn}W(CO)5]+¬CB11H12–. Jedná seo aqua komplex organocínatého kationtu , jehož struktura byla určena pomocí rentgenové difrakční analýzy.	Aqua Komplex; Organocínatý kationtu; struktura
eng	[{2,6-(Me2NCH2)2C6H3(H2O)Sn}W(CO)5]+¬CB11H12–: Aqua Complex of a Transition-Metal-Bound Organotin(II) Cation versus an Ammonium-Type Structure,	The molecular structures of the intramolecularly coordinated tungstenpentacarbonyl organostannylene complexes 2,6-(Me2NCH2)2C6H3(Cl)SnW(CO)5 and [2,6-(Me2NCH2)2C6H3(H2O)SnW(CO)5]+(CB11H12)– are reported. The latter compound is an aqua complex in which the water molecule replaces one of the two N→Sn coordination sites. The coordination of the water molecule is accompanied by proton transfer to the nitrogen atom. DFT calculations reveal this to be the thermodynamically most-stable structure.	Aqua Complex; Transition-Metal-Bound; Organotin(II); Cation;

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