Publication detail

Structure, Properties and Comparison of C,N-chelated and Amidostabilized Plumbylenes

Year: 2010

Type of publication: článek v odborném periodiku

Name of source: Collection of Czechoslovak Chemical Communications

Publisher name: Ústav organické chemie a biochemie AV ČR

Place: Praha

Page from-to: 121-131

Titles:

Language	Name	Abstract	Keywords
cze	Struktura, vlastnosti a srovnání C,Nchelatovaných a amido stabilizovaných plumbylenů	Struktura molekuly {2 - [2)NCH2]C6H4}(2)Pb (1) v pevné fázi byla určená rentgenovou difrakcí na monokrystalickém materiále. Komplexy stabilizované objemnými amido ligandy [(i-C3H7)(2)C6H3]NHLi (2) a [(i-C3H7)(2)C6H3N(Me3Si)](2)Pb (3) byly syntetizované a charakterizované v pevné fázi a roztoku H-1, C-13, N-15 a Pb-207 NMR a XRD technikami. Struktura obou C,N-chelatovaných a objemných amido plumbylenů je srovnána.	olovo, amidy, C,N chelatující ligandy, plumbyleny, Xray difrakce
eng	Structure, Properties and Comparison of C,N-chelated and Amidostabilized Plumbylenes	The molecular structure of {2-[(CH3)(2)NCH2]C6H4}(2)Pb (1) in the solid state was determined by X-ray diffraction techniques on a single crystalline material. Bulky amido ligand stabilized complexes [(i-C3H7)(2)C6H3]NHLi (2) and [(i-C3H7)(2)C6H3N(Me3Si)](2)Pb (3) were synthesized and characterized both in the solid state and solution by H-1, C-13, N-15 and Pb-207 NMR and XRD techniques. The structure of both C,N-chelated and bulky amido plumbylenes is compared.	Lead; Bulky amides; C,N-chelates; Plumbylenes; Organoelement chemistry; X-ray diffraction

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