Publication detail

C,N-chelated Organotin(IV) Trifluoroacetates. Instability of the Mono- and Diorganotin(IV) Derivatives

Year: 2011

Type of publication: článek v odborném periodiku

Name of source: Journal of Organometallic Chemistry

Page from-to: 676-686

Titles:

Language	Name	Abstract	Keywords
cze	C,N chelatované organocíničité trifluoracetáty. Nestabilita mono a diorganocíničitých derivátů.	C,N chelatované tri, di a monoorganocíničité halogenidy byly podrobeny reakci s ekvimolárním množstvím CF 3COOAg za vzniku odpovídajícího C,N chelatovaného organocíničitého trifluoroacetatu. Byl připraven a charakterizován set tri, di a monoorganocíničitých trifluoracetátů nesoucích L CN (kde L CN je 2-(N,N-dimethylaminomethyl)fenyl-). Charakterizace byla provedena pomocí X-ray difrakční analýzy, multinukleární NMR a IR spektroskopie.	organocíničité trifluoracetáty
eng	C,N-chelated Organotin(IV) Trifluoroacetates. Instability of the Mono- and Diorganotin(IV) Derivatives	The C,N-chelated tri-, di- and monoorganotin(IV) halides react with equimolar amounts of CF 3COOAg to give corresponding C,N-chelated organotin(IV) trifluoroacetates. The set of prepared tri-, di- and monoorganotin(IV) trifluoroacetates bearing the L CN ligand (where L CN is 2-(N,N-dimethylaminomethyl)phenyl-) was structurally characterized by X-ray diffraction analyses, multinuclear NMR and IR spectroscopy. In the case of triorganotin(IV) trifluoroacetates and (L CN) 2Sn(OC(O)CF 3) 2, no tendency to form hydrolytic products, or instability towards the moisture was observed. L CNRSn(OC(O)CF 3) 2 (where R is n-Bu or Ph) and L CNSn(OC(O)CF 3) 3 forms upon crystallization from THF in the air mainly dinuclear complexes in which the two tin atoms are interconnected either by hydroxo-bridges or by an oxo-bridge and/or by a bridging trifluoroacetate(s).	Organotin(IV) Trifluoroacetates

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