Publication detail

C,N-chelated dicyclopentadienylzirconium complexes and their possible use as hydrogenation catalysts

Authors: Bareš Josef | Padělková Zdeňka | Meunier Philippe | Pirio Nadine | Růžička Aleš

Year: 2010

Type of publication: článek v odborném periodiku

Name of source: Inorganic Chemistry Communications

Publisher name: Elsevier Science BV

Place: Amsterdam

Page from-to: 1512-1514

Titles:

Language	Name	Abstract	Keywords
cze	C,Nchelatované dicyklopentadienylzirkoničité komplexy a jejich použití jako hydrogenačních katalyzátorů	In situ generovaný Cp2Zr(n-Bu)Cl (6) byl podroben reakci s {2-[(CH3)2NCH2]C6H4}2Pb za vzniku {2-[(CH3)2NCH2]C6H4}Cp2ZrCl (7), [(CH3)2NCH2]C6H5, butanu a elementárního Pb. Další deriváty chlorid (7), fluorid (8), hydrid (9), methyl derivát (10) a redukční produkt od 7 byly také popsány. Byly popsány i krystalové struktury od sloučenin 7-10. Byla testována katalytická aktivita od 9 a 10 při hydrogenaci styrenu.	dicyklopentadienylzirkoničité komplexy, hydrogenační katalyzátory
eng	C,N-chelated dicyclopentadienylzirconium complexes and their possible use as hydrogenation catalysts	In situ generated Cp2Zr(n-Bu)Cl (6) reacts with {2-[(CH3)2NCH2]C6H4}2Pb to form exclusively {2-[(CH3)2NCH2]C6H4}Cp2ZrCl (7), [(CH3)2NCH2]C6H5, butene and elemental lead. The further derivatization of chloride (7) to fluoride (8), hydride (9), methyl derivative (10), and a reduction of 7 are also described. The crystal structures of 7–10 were determined. The catalytic activity of 9 and 10 in hydrogenation of styrene was also preliminarily tested	dicyclopentadienylzirconium complexes, hydrogenation catalysts

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