Publication detail

[{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(mu-OH)W(CO)(5)](2): A Transition-Metal-Coordinated Organotin(II) Hydroxide.

Authors: Jambor Roman | Herres-Pawlis Sonja | Schuermann Markus | Jurschat Klaus

Year: 2011

Type of publication: článek v odborném periodiku

Name of source: European Journal of Inorganic Chemistry

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 344-348

Titles:

Language	Name	Abstract	Keywords
cze	[{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(mu-OH)W(CO)(5)](2): Organocínatý hydroxid	Byla provedena syntéza intramolekulárně koordinovaných organocínatých sloučenin {2,6-Me2NCH2)2C6H3}Sn(H)W(CO)5 (2) a [{2,6-(Me2NCH2)2-C6H3}Sn(μ-OH)W(CO)5]2 (3). Molekulová struktura sloučeniny 3 byla určena pomocí X-ray analýzy.	Cín;wolfram;kalkulace;organocínatý hydroxid;vodíková vazba
eng	[{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(mu-OH)W(CO)(5)](2): A Transition-Metal-Coordinated Organotin(II) Hydroxide.	The synthesis of the intramolecularly coordinated pentacarbonyltungsten– organostannylene complexes {2,6-(Me2NCH2)2C6H3}Sn(H)W(CO)5 (2) and [{2,6-(Me2NCH2)2-C6H3}Sn(μ-OH)W(CO)5]2 (3) and the solid-state molecular structure of 3, as determined by single-crystal X-ray diffraction analysis, are reported. Compound 3 is characterized by hydroxido bridges [Sn–O 2.068(5), 2.231(5) Å], an intramolecular NSn coordination bond [2.501(7) Å] and an intramolecular O–H···N hydrogen bond [O···N 2.715(8) Å].	Tin;Tungsten;X-ray diffraction;Density functional calculations;Organotin hydroxides;Hydrogen bonds

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