Publication detail

Intramolecularly Coordinated [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+): A Strong sigma Donor for Pt(II).

Authors: Martincová Jana | Dostál Libor | Herres-Pawlis Sonja | Růžička Aleš | Jambor Roman

Year: 2011

Type of publication: článek v odborném periodiku

Name of source: Chemistry - A European Journal

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 7423-7427

Titles:

Language	Name	Abstract	Keywords
cze	Intramolekulárně koordinovaný organocínatý kation [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+). Donor pro Pt(II)	Byl připraven neočekávaný komplex [Pt(LSn)(μ2-pyt)2Cl] (L=2,6-(Me2NCH2)2C6H3−), kde Sn←N koordinovaný stannylideniový kation (LSnII)+ donuje [Pt(pyt)2Cl]− anion.	organocínatý kation;platinový komplex;rentgenová difrakční analýza
eng	Intramolecularly Coordinated [{2,6-(Me(2)NCH(2))(2)C(6)H(3)}Sn(II)](+): A Strong sigma Donor for Pt(II).	The synthesis of the unprecedented complex [Pt(LSn)(μ2-pyt)2Cl] (L=2,6-(Me2NCH2)2C6H3−), in which a Sn←N-coordinated stannylidenium (LSnII)+ fragment donates to a [Pt(pyt)2Cl]− anion, is reported. The natural-bond-orbital analysis revealed that the lone electron pair of the stannylidenium (LSnII)+ fragment is shared by tin and platinum atoms and the charge of the Sn atom is +1.709.	organotin(II);platinum;X-ray difraction

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