Publication detail

Oxidation of Intramolecularly Coordinated Distannyne by S(8): From Tin(I) to Tin(IV) Polysulfide Via Tin(II) Sulfide.

Authors: Bouška Marek | Dostál Libor | Růžička Aleš | Beneš Ludvík | Jambor Roman

Year: 2011

Type of publication: článek v odborném periodiku

Name of source: Chemistry - A European Journal

Publisher name: Wiley-VCH

Place: Weinheim

Page from-to: 450-454

Titles:

Language	Name	Abstract	Keywords
cze	Oxidace intramolekulárně koodinovaného distannynu sírou: Syntéza organocíničitého polysulfidu	Redoxní reakce distannynu 1 s S8 vedla k syntéze organocínatého sulfidu [({2,6-(Me2NCH2)2C6H3}Sn)2S] (2) a organocíničitého polysulfudu [({2,6-(Me2NCH2)2C6H3}Sn(μ-S))2(μ-S5)] (3).	organocíničité;organocínaté;sulfidy
eng	Oxidation of Intramolecularly Coordinated Distannyne by S(8): From Tin(I) to Tin(IV) Polysulfide Via Tin(II) Sulfide.	The redox reaction of distannyne 1 with S8 allowed the synthesis of organotin(II) sulfide [({2,6-(Me2NCH2)2C6H3}Sn)2S] (2) in the first step of the oxidation. The second step afforded the isolation of the heptathiadistannabicyclo[1.1.5]nonane [({2,6-(Me2NCH2)2C6H3}Sn(μ-S))2(μ-S5)] (3)—a new organotin(IV) polysulfide.	organotin;oxidation;sulfide

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