Publication detail

Intramolecularly Coordinated Stannanechalcogenones: X-ray Structure of [2,6-(Me2NCH2)2C6H3](Ph)Sn=Te

Year: 2011

Type of publication: článek v odborném periodiku

Name of source: Organometallics

Publisher name: American Chemical Society

Place: Washington

Page from-to: 5904-5910

Titles:

Language	Name	Abstract	Keywords
cze	Intramolekulárně koordinované stannachalkogenidy: Syntéza monomerního [2,6-(Me2NCH2)2C6H3](Ph)Sn=Te	Byly připraveny diorganocíničité chalkogenidy [{2,6-(Me2NCH2)2C6H3}(Ph)Sn(mu-S)]2 (2) a monomerní [{2,6-(Me2NCH2)2C6H3}(Ph)Sn=E] (E = Se (3), Te(4)). Byla studována jejich struktura a vlastnosti.	Organokovy;syntéza;struktura
eng	Intramolecularly Coordinated Stannanechalcogenones: X-ray Structure of [2,6-(Me2NCH2)2C6H3](Ph)Sn=Te	The treatment of an intramolecularly coordinated organotin(IV) dichloride, [2,6-(Me2NCH2)2C6H3](Ph)SnCl2 (1), with Li2E (E = S, Se, Te) afforded thermally stable dimeric diarylstannanethione [{2,6-(Me2NCH2)2C6H3}(Ph)Sn(mu-S)]2 (2) and monomeric diarylstannaneselone and -tellurone [{2,6-(Me2NCH2)2C6H3}(Ph)Sn=E] (E = Se (3), Te (4)). Compounds 2?4 were characterized by means of elemental analyses and 1H, 13C, 77Se, 119Sn, and 125Te NMR spectroscopy. The molecular structures of 2 and 4 were determined by single-crystal X-ray diffraction analysis. Solution NMR studies revealed dependence of the structure of compounds 2 and 3 on the solvent (C6D6 or CDCl3). In addition, the synthesis of dimeric stannanetellurone [{2,6-(Me2NCH2)2C6H3}(Bu)Sn(mu-Te)]2 (5) showed an influence of the organic group R (R = Bu or Ph) on the structure of diorganotin(IV) tellurides 4 and 5.	Organometals;synthesis;structure

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