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Study of TATP: Formation of new chloroderivates of triacetone triperoxide
Authors: Matyáš Robert | Jirásko Robert | Lyčka Antonín | Pachmáň Jiří
Year: 2011
Type of publication: článek v odborném periodiku
Name of source: Propellants Explosives Pyrotechnics
Publisher name: Wiley-VCH
Place: Weinheim
Page from-to: 219-224
Titles:
Language Name Abstract Keywords
cze Studie TATP: Vznik nových chlorovaných derivátů triaceton triperoxidu Metodami HPLC/MS/MS a NMR byl v produktu reakce acetonu s peroxidem vodíku v nadbytku kyseliny chlorovodíkové (molární poměr kyselina chlorovodíková/aceton nc/na = 2,5) prokázán vznik dvou nových chlorovaných cyklických peroxidů acetonu - 3-(chloromethyl)-3,6,6,9,9-pentamethyl-1,2,4,5,7,8-hexoxonanu a 3,6-bis(chloromethyl)-3,6,9,9-tetramethyl-1,2,4,5,7,8-hexoxonanu. Podrobnosti analýzy a reakčních podmínek, za kterých tyto nesymetrické peroxidy vznikají, jsou popsány v článku. 3-(chloromethyl)-3,6,6,9,9-pentamethyl-1,2,4,5,7,8-hexoxonan;3,6-bis(chloromethyl)-3,6,9,9-tetramethyl-1,2,4,5,7,8-hexoxonan;3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexoxonan;TATP;hmotnostní spektroskopie;NMR
eng Study of TATP: Formation of new chloroderivates of triacetone triperoxide The existence of two new types of chloroderivates of cyclic acetone peroxides - 3-(chloromethyl)-3,6,6,9,9-pentamethyl-1,2,4,5,7,8-hexoxonane and 3,6-bis(chloromethyl)-3,6,9,9-tetramethyl-1,2,4,5,7,8-hexoxonane was proved by HPLC/MS/MS and NMR in the reaction products when acetone and hydrogen peroxide are mixed in the presence of excess hydrochloric acid (molar ratio hydrochloric acid to acetone nc/na = 2.5). The details of analysis, and the conditions under which these asymmetric chloroderivates of cyclic peroxides form, are described. 3-(chloromethyl)-3,6,6,9,9-pentamethyl-1,2,4,5,7,8-hexoxonane;3,6-bis(chloromethyl)-3,6,9,9-tetramethyl-1,2,4,5,7,8-hexoxonane;3,3,6,6,9,9-hexamethyl-1,2,4,5,7,8-hexoxonane;TATP;mass spectrometry;NMR

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