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Solid State Field-Assisted Diffusion of Copper in Multi-Component Tellurite Glass
Authors: Stepanov Boris | Ren Jing | Wágner Tomáš | Lorincik Jiří | Frumar Miloslav | Churbanov Mikhail | Chigirinsky Yuri
Year: 2011
Type of publication: článek v odborném periodiku
Name of source: Journal of the American Ceramic Society
Publisher name: Blackwell Publishing
Place: Malden
Page from-to: 1986-1988
Titles:
Language Name Abstract Keywords
cze Difuze mědi v multikomponentních teluritových sklech Tato práce se zabývá přípravou multikomponentních teluritových skel s přídavkem mědi. difuze;měď;telurit;sklo
eng Solid State Field-Assisted Diffusion of Copper in Multi-Component Tellurite Glass In this work, we have prepared copper-doped multicomponent tellurite glasses by solid state electric field-assisted diffusion. The concentration profiles of the elements have been measured by the secondary ion mass spectrometry. The depth profile of copper can be well fitted only by a modified erfc-like solution of the second Fick's law which assumes that both the Cu(+) and Cu(2+) ions are involved in the diffusion. The modeling shows that the Cu(2+) ions are much more mobile than the Cu(+) ones in the tellurite glasses and affected strongly by the applied electric field. Our results demonstrate the possibility of fabricating copper-doped planar waveguides based on the tellurite glasses. Solid State Field-Assisted Diffusion;Copper;Tellurite Glass