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Stabilization of an Intramolecularly Coordinated Stannylidenium Cation
Authors: Martincová Jana | Dostál Libor | Růžička Aleš | Herres-Pawlis Sonja | Jambor Roman
Year: 2012
Type of publication: článek v odborném periodiku
Name of source: Zeitschrift für anorganische und allgemeine Chemie
Publisher name: Wiley-VCH
Place: Weinheim
Page from-to: 1672-1675
Titles:
Language Name Abstract Keywords
cze Stabilizace cínatých kationtů Byla připravena sloučenina obsahující stannylideniový kation koordinovaný na atom platiny. byla popsaána vazebná situace pomocí DFT kalkulací Chelátující ligand, cín, platina, NMR spektroskopie, kovová vazba
eng Stabilization of an Intramolecularly Coordinated Stannylidenium Cation The treatment of trans-{[2, 6-(Me2NCH2)2C6H3]SnI}2PtI2 with Na(pyt) (pyt = 2-mercaptopyridine) yielded the unprecedented complex {{[2, 6-(Me2NCH2)2C6H3]Sn}Pt(mu-pyt)2I} (1), where a Sn?N coordinated stannylidenium (LSnII)+ fragment donates a to a [PtII(pyt)2I] anion. Compound 1 was characterized by NMR spectroscopy and molecular structure was determined by X-ray diffraction analysis. The bonding situation in 1 was analyzed by DFT studies. Chelating ligand; Tin; Platinum; NMR spectroscopy; Metal bonding