Publication detail

Effect of preparation method on nature and distribution of vanadium species in vanadium-based hexagonal mesoporous silica catalysts: Impact on catalytic behavior in propane ODH

Year: 2012

Type of publication: článek v odborném periodiku

Name of source: Applied catalysis A: General

Publisher name: Elsevier Science BV

Place: Amsterdam

Page from-to: 29-39

Titles:

Language	Name	Abstract	Keywords
cze	Efekt přípravy na povahu a distribuci typů vanadia v katalyzatorech založených na hexagonální mezoporézn silice: Vliv na katalytické chování v ODH propanu	Tato práce srovnává katalytické chování VOx-HMS katalyzátorů připravených impregnační metodou a přímou syntézou. Řadou technik jako jsou XRD, XRF, SEM, N2 adsorpce, H2 TP a DR-UV-VIS bylo studováno zastoupení jednitlivých typů VOx komplexů v katalyzátoru. Katalytická aktivita byla zkoušena v oxidativní dehydrogenaci priopranu.	vanad; ODH; propan: propen; mezoporézní silika; TPR; UV-vis; HMS
eng	Effect of preparation method on nature and distribution of vanadium species in vanadium-based hexagonal mesoporous silica catalysts: Impact on catalytic behavior in propane ODH	This work reports comparative study of catalytic performance of VOx-HMS catalysts prepared by ethanolic impregnation method and direct synthesis. In order to detailed investigation of vanadium speciation depending on vanadium content and its impact on catalytic behavior in C3-ODH, number of samples in wide range of vanadium content (1-16 wt.%) was prepared by both types of preparation. Prepared catalysts were tested in the oxidative dehydrogenation of propane at 540 degrees C under different contact times and catalytic results were correlated with physicochemical characteristics of the catalysts examined by XRD, XRF, SEM, N-2 adsorption/desorption isotherms, H-2-TPR and DR-UV-visible spectroscopy. Study led to conclusion, that (i) both monomeric VOx complexes and oligomeric VOx complexes with tetrahedral coordination containing V-O-V bonds are active and selective catalytic sites for C3-ODH, (ii) active VOx species are characterized by distinct reduction peak in H-2-TPR pattern centered at 570-590 degrees C, (iii) VOx-HMS vanadosilicates can be directly synthesized under ambient conditions without need for autoclave in wide range of vanadia loading with preservation of good catalytic performance and (iv) the catalytic results in C3-ODH were significantly better for synthesized catalysts compared to impregnated catalysts resulting in three times higher propene productivity of the best synthesized catalyst compared to the best impregnated one under the same reaction conditions. The higher is vanadium loading the more distinct is the difference in catalytic performance of both types of catalysts.	vanadium; ODH; propane; propene; mesoporous silica; TPR; UV-vis; HMS

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